Fate of polyaromatic hydrocarbons in the pyrolysis of industrial waste oils

被引:27
作者
Domeño, C [1 ]
Nerín, C [1 ]
机构
[1] Univ Zaragoza, Dept Quim Analit, Ctr Politecn Super, E-50015 Zaragoza, Spain
关键词
PAHs; analysis; waste oils; HPLC; pyrolysis;
D O I
10.1016/S0165-2370(02)00064-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Four different waste oils have been pyrolyzed using an experimental bench scale pyrolysis unit at 600 degreesC under atmospheric pressure and the polyaromatic hydrocarbons (PAHs) have been analyzed in the valuable liquid fraction. After the appropriate digestion and extraction procedures, the individual PAHs were quantified in each case by HPLC-UV. Toxicity of the PAHs mixture obtained in the liquid fraction resulting from the pyrolysis of machine waste oil, automotive waste oil, hydraulic waste oil and cutting waste oil as well as the PAHs profile are compared and discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:237 / 246
页数:10
相关论文
共 17 条
  • [1] Temperature dependence of Henry's law constants of thirteen polycyclic aromatic hydrocarbons between 4°C and 31°C
    Bamford, HA
    Poster, DL
    Baker, JE
    [J]. ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 1999, 18 (09) : 1905 - 1912
  • [2] Thermal degradation of halogen-free flame retardant epoxides and polycarbonate in air
    Becker, L
    Lenoir, D
    Matuschek, G
    Kettrup, A
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2001, 60 (01) : 55 - 67
  • [3] Pyrolysis of auto shredder residue: experiments with a laboratory screw kiln reactor
    Day, M
    Shen, Z
    Cooney, JD
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) : 181 - 200
  • [4] DOMENO C, 1998, THESIS U ZARAGOZA
  • [5] GOLDSTEIN LS, 1994, POLYCYCL AROMAT COMP, V7, P161, DOI 10.1080/10406639408014726
  • [6] Valuable products from mineral waste oils containing heavy metals
    Lázaro, MJ
    Moliner, R
    Suelves, I
    Nerín, C
    Domeño, C
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2000, 34 (15) : 3205 - 3210
  • [7] State of the art of applied fast pyrolysis of lignocellulosic materials - a review
    Meier, D
    Faix, O
    [J]. BIORESOURCE TECHNOLOGY, 1999, 68 (01) : 71 - 77
  • [8] The temporal variability of the profile of carcinogenic polycyclic aromatic hydrocarbons in urban air: a study in a medium traffic area in Rome, 1993-1998
    Menichini, E
    Monfredini, F
    Merli, F
    [J]. ATMOSPHERIC ENVIRONMENT, 1999, 33 (23) : 3739 - 3750
  • [9] Distribution of Pb, V, Cr, Ni, Cd, Cu and Fe in particles formed from the combustion of waste oils.
    Nerín, C
    Domeño, C
    García, JI
    del Alamo, A
    [J]. CHEMOSPHERE, 1999, 38 (07) : 1533 - 1540
  • [10] Nerin C, 1998, QUIM ANAL, V17, P75