Second-order off-diagonal hyperpolarizability tensor components of substituted carbazoles by hyper-Rayleigh scattering depolarization measurements

被引：26

作者：

Boutton, C

Clays, K

Persoon, A

Wada, T

Sasabe, H

机构：

[1] Univ Louvain, Dept Chem, Ctr Res Mol Electr & Photon, Lab Chem & Biol Dynam, B-3001 Heverlee, Belgium

[2] Univ Arizona, Ctr Opt Sci, Tucson, AZ 85721 USA

[3] RIKEN, Inst Phys & Chem Res, Wako, Saitama 35101, Japan

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 286卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(98)00040-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The tensor components of the molecular first hyperpolarizability of 3,6-dinitro-9-ethylcarbazole and 3-nitro-9-ethylcarbazole have been analyzed with hyper-Rayleigh scattering and electric-field-induced second-harmonic generation. We show that measurements of the depolarization ratio give information directly about the importance of the off-diagonal molecular tensor components. (C) 1998 Published by Elsevier Science B.V.

引用

收藏

页码：101 / 106

页数：6

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