Cruciform π-systems for molecular electronics applications

被引：112

作者：

Klare, JE ^{[1
]}

Tulevski, GS ^{[1
]}

Sugo, K ^{[1
]}

de Picciotto, A ^{[1
]}

White, KA ^{[1
]}

Nuckolls, C ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 20期

关键词：

D O I：

10.1021/ja0350942

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study details a modular and general synthesis of a new class of molecules consisting of cruciform π-systems. The key to synthesizing these molecules was an unprecedented double Staudinger cyclization. Once formed, these rigid compounds assemble into ordered monolayer films on metal and metal oxide surfaces to orient their conjugated, bis-phenyloxazole subunits upright. This surface orientation is enforced by the external phenyl substituents that are out of the ring plane, thus preventing the prone conformation. Copyright © 2003 American Chemical Society.

引用

页码：6030 / 6031

页数：2

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[11] Formation and patterning of self-assembled monolayers derived from long-chain organosilicon amphiphiles and their use as templates in materials microfabrication [J].