Polyazido high-nitrogen compounds: Hydrazo- and azo-1,3,5-triazine

被引：282

作者：

Huynh, MHV

Hiskey, MA

Hartline, EL

Montoya, DP

Gilardi, R

机构：

[1] Los Alamos Natl Lab, Mat Dynam Grp, Dynam Expt Div, Los Alamos, NM 87545 USA

[2] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 37期

关键词：

azides; explosives; heat of formation; high energy-density materials (HEDM); nitrogen;

D O I：

10.1002/anie.200460366

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

20 nitrogens and six carbons: The compounds 1 and 2, demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high-nitrogen compounds and also decrease their volatility. The compound 2 has the highest experimentally measured heat of formation reported for energetic organic compounds (+ 2171 kJ mol-1).

引用

页码：4924 / 4928

页数：5

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