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Polyazido high-nitrogen compounds: Hydrazo- and azo-1,3,5-triazine

被引：282
作者：
Huynh, MHV
Hiskey, MA
Hartline, EL
Montoya, DP
Gilardi, R
机构：
[1] Los Alamos Natl Lab, Mat Dynam Grp, Dynam Expt Div, Los Alamos, NM 87545 USA
[2] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 37期
关键词：
azides; explosives; heat of formation; high energy-density materials (HEDM); nitrogen;
D O I：
10.1002/anie.200460366
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
20 nitrogens and six carbons: The compounds 1 and 2, demonstrate that hydrazo and azo linkages can be used to desensitize polyazido high-nitrogen compounds and also decrease their volatility. The compound 2 has the highest experimentally measured heat of formation reported for energetic organic compounds (+ 2171 kJ mol-1).
引用
收藏
页码：4924 / 4928
页数：5
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