Synthesis of carbon nanotubes using a novel catalyst derived from hydrotalcite-like Co-Al layered double hydroxide precursor

被引:90
作者
Li, F [1 ]
Tan, Q [1 ]
Evans, DG [1 ]
Duan, X [1 ]
机构
[1] Beijing Univ Chem Technol, Minist Educ Key Lab Sci & Technol Controllable Ch, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanotubes; chemical vapor deposition; layered double hydroxide;
D O I
10.1007/s10562-005-2107-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present letter, for the first time, the efficacy of hydrotalcite-like layered double hydroxides (LDHs) materials as alternative and novel catalyst precursors for the synthesis of carbon nanotubes (CNTs) via catalytic chemical vapor deposition (CCVD) of acetylene was reported. Nanometer-sized cobalt particles were prepared by calcination of a single molecular LDH precursor containing cobalt (II) and aluminum (III) and following by a process of reduction. Multi-walled CNTs with uniform diameters were obtained using the as-synthesized catalyst in the reaction.
引用
收藏
页码:151 / 156
页数:6
相关论文
共 16 条
[11]   Stoichiometric synthesis of a pure ferrite from a tailored layered double hydroxide (hydrotalcite-like) precursor [J].
Liu, JJ ;
Li, F ;
Evans, DG ;
Duan, X .
CHEMICAL COMMUNICATIONS, 2003, (04) :542-543
[12]   In situ investigation of the thermal decomposition of Co-Al hydrotalcite in different atmospheres [J].
Pérez-Ramírez, J ;
Mul, G ;
Kapteijn, F ;
Moulijn, JA .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (03) :821-830
[13]   Production of differently shaped multi-wall carbon nanotubes using various cobalt supported catalysts [J].
Piedigrosso, P ;
Konya, Z ;
Colomer, JF ;
Fonseca, A ;
Van Tendeloo, G ;
Nagy, JB .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (01) :163-170
[14]   Effect of hydrogen on the orientation of carbon layers in deposits from the carbon monoxide disproportionation reaction over Co/Al2O3 catalysts [J].
Pinheiro, P ;
Schouler, MC ;
Gadelle, P ;
Mermoux, M ;
Dooryhée, E .
CARBON, 2000, 38 (10) :1469-1479
[15]   Raman spectroscopy and field-emission properties of CVD-grown carbon-nanotube films [J].
Sveningsson, M ;
Morjan, RE ;
Nerushev, OA ;
Sato, Y ;
Bäckström, J ;
Campbell, EEB ;
Rohmund, F .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2001, 73 (04) :409-418
[16]   Crystalline ropes of metallic carbon nanotubes [J].
Thess, A ;
Lee, R ;
Nikolaev, P ;
Dai, HJ ;
Petit, P ;
Robert, J ;
Xu, CH ;
Lee, YH ;
Kim, SG ;
Rinzler, AG ;
Colbert, DT ;
Scuseria, GE ;
Tomanek, D ;
Fischer, JE ;
Smalley, RE .
SCIENCE, 1996, 273 (5274) :483-487