Airborne spectroscopic observations of chlorine activation and denitrification of the 1999/2000 winter Arctic stratosphere during SOLVE

[1] We have used Fourier transform spectrometers aboard the NASA DC-8 and on balloons as part of the SAGE III Ozone Loss and Validation Experiment (SOLVE) to record infrared absorption spectra of the polar stratosphere. From the high-resolution aircraft spectra we derived vertical column amounts of HCl, HF, NO2, HNO3, and a number of other gases for 11 flights in the region of the northern polar vortex. Vertical mixing ratio profiles are derived for a number of gases from two balloon flights. Within the vortex, where low values of total ozone are observed during the latter part of the observation period, we observed markedly reduced columns of HCl and NO2 and elevated columns of HF and HNO3 relative to columns outside the vortex. The low value for the ratio of HCl to HF indicates that HCl had been chemically or physically removed, probably providing a source for active chlorine. High values of HNO3 inside the vortex indicate that nitrogen oxides, which might otherwise mitigate chlorine-catalyzed ozone destruction, have been converted into more stable reservoirs. Because of incorporation into particles, some nitric acid may be removed from the stratosphere altogether.