The characterisation and reactivity of (η5-C5H5)M(CO)3(Xe) (M = Nb or Ta) in solution at room temperature

被引：15

作者：

Grills, DC ^{[1
]}

Childs, GI ^{[1
]}

George, MW ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b004843g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Employing fast time-resolved infrared (TRIR) spectroscopy we have characterised CpM(CO)(3)(Xe) (M = Nb or Ta) at room temperature in supercritical Xe solution; CpM(CO)(3)(Xe) were found to exhibit a similar reactivity with CO to the corresponding alkane complexes, CpM(CO)(3)(n-heptane) and we report a trend in reactivity of the early transition metal Xe complexes.

引用

页码：1841 / 1842

页数：2

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