Lithium insertion/extraction reaction on crystalline MoO3

被引：147

作者：

Tsumura, T ^{[1
]}

Inagaki, M ^{[1
]}

机构：

[1] Hokkaido Univ, Fac Engn, Kita Ku, Sapporo, Hokkaido 060, Japan

来源：

SOLID STATE IONICS | 1997年 / 104卷 / 3-4期

关键词：

molybdenum trioxide; XRD measurement; van der Waals gap; co-insertion of solvent;

D O I：

10.1016/S0167-2738(97)00418-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrochemical lithium insertion/extraction reaction on three MoO3 samples with different crystallinity, which were heat-treated at 300, 600, and 750 degrees C, was studied, and the structural change of the host MoO3 during the lithium insertion/extraction process was followed by XRD measurements on the oriented cathode plates in a reflection and transmission arrangement. The possibility of the insertion of solvated lithium ions into the van der Waals gap and of the accommodation of some of the lithium ions into the sites in the Mo-O octahedron layers were expected. A scheme of lithium insertion into crystalline MoO3 was discussed.

引用

页码：183 / 189

页数：7

共 16 条

[1] ELECTROCHROMISM AND PHOTOCHROMISM IN MOO-3 FILMS [J].

ARNOLDUSSEN, TC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (04) :527-531

[2] CHARACTERISTICS OF MOLYBDENUM OXIDE AND CHROMIUM-OXIDE CATHODES IN PRIMARY AND SECONDARY ORGANIC ELECTROLYTE LITHIUM BATTERIES .2. TRANSPORT-PROPERTIES [J].

BESENHARD, JO ;

HEYDECKE, J ;

WUDY, E ;

FRITZ, HP ;

FOAG, W .

SOLID STATE IONICS, 1983, 8 (01) :61-71

[3] CHARACTERISTICS OF MOLYBDENUM OXIDE AND CHROMIUM-OXIDE CATHODES IN PRIMARY AND SECONDARY ORGANIC ELECTROLYTE LITHIUM BATTERIES .1. MORPHOLOGY, STRUCTURE AND THEIR CHANGES DURING DISCHARGE AND CYCLING [J].

BESENHARD, JO ;

HEYDECKE, J ;

FRITZ, HP .

SOLID STATE IONICS, 1982, 6 (03) :215-224

[4]

BESENHARD JO, 1976, J POWER SOURCES, V1, P267

[5] A HIGH-RESOLUTION DILATOMETER FOR INSITU STUDIES OF THE ELECTROINTERCALATION OF LAYERED MATERIALS [J].

BIBERACHER, W ;

LERF, A ;

BESENHARD, JO ;

MOHWALD, H ;

BUTZ, T .

MATERIALS RESEARCH BULLETIN, 1982, 17 (11) :1385-1392

[6] PHASE RELATIONSHIPS IN SYSTEM HXMOO3 (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2.0) [J].

BIRTILL, JJ ;

DICKENS, PG .

MATERIALS RESEARCH BULLETIN, 1978, 13 (04) :311-316

[7] AMORPHOUS CATHODE MATERIALS IN LITHIUM-ORGANIC ELECTROLYTE CELLS - TUNGSTEN AND MOLYBDENUM TRIOXIDES [J].

BONINO, F ;

BICELLI, LP ;

RIVOLTA, B ;

LAZZARI, M ;

FESTORAZZI, F .

SOLID STATE IONICS, 1985, 17 (01) :21-28

[8] OPTICAL PROPERTIES AND COLOR-CENTER FORMATION IN THIN FILMS OF MOLYBDENUM TRIOXIDE [J].

DEB, SK ;

CHOPOORIAN, JA .

JOURNAL OF APPLIED PHYSICS, 1966, 37 (13) :4818-+

[9] ELASTIC AND INELASTIC NEUTRON STUDIES OF HYDROGEN MOLYBDENUM BRONZES [J].

DICKENS, PG ;

BIRTILL, JJ ;

WRIGHT, CJ .

JOURNAL OF SOLID STATE CHEMISTRY, 1979, 28 (02) :185-193

[10] INFLUENCE OF THE GROWTH-CONDITIONS ON ELECTROCHEMICAL FEATURES OF MOO3 FILM-CATHODES IN LITHIUM MICROBATTERIES [J].

JULIEN, C ;

NAZRI, GA ;

GUESDON, JP ;

GORENSTEIN, A ;

KHELFA, A ;

HUSSAIN, OM .

SOLID STATE IONICS, 1994, 73 (3-4) :319-326

← 1 2 →