Phase diagrams of polydisperse van der Waals fluids

被引：50

作者：

Bellier-Castella, L ^{[1
]}

Xu, H

Baus, M

机构：

[1] Univ Lyon 1, Dept Phys Mat, CNRS, UMR 5586, F-69622 Villeurbanne, France

[2] Free Univ Brussels, B-1050 Brussels, Belgium

来源：

JOURNAL OF CHEMICAL PHYSICS | 2000年 / 113卷 / 18期

关键词：

D O I：

10.1063/1.1316007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phase behavior of a system composed of spherical particles with a monomodal size distribution is investigated theoretically within the context of the van der Waals approximation for polydisperse fluids. It is shown how the binodals, spinodals, cloud-point and shadow curves as well as all the (polydispersity induced) critical points can be obtained for a variety of interaction potentials. The polydispersity induced modifications of the phase diagram (even for a polydispersity index I as small as I approximate to1.01) should be observable in some colloidal dispersions. (C) 2000 American Institute of Physics. [S0021-9606(00)51842-X].

引用

页码：8337 / 8347

页数：11

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