14e η1-hydrocarbyliron complexes supported by hydrotris(3,5-diisopropylpyrazolyl)borate:: The allyl complex prefers a highly coordinatively unsaturated 14e η1-structure to a 16e η3-structure

被引：41

作者：

Akita, M ^{[1
]}

Shirasawa, N ^{[1
]}

Hikichi, S ^{[1
]}

Moro-Oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a801460d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordinatively unsaturated allyl and benzyl complexes with the hydrotris(3,5-diisopropylpyrazolyl)borat ligand(Tp(iPr)), Tp(iPr)M-allyl(M = Ni, Co, Fe) and Tp(iPr)Fe-p-methylbenzyl, are prepared and characterized by X-ray crystallography, and the allyl ligand is coordinated to the Fe center in a eta(1)-fashion to form a 14e species in contrast to the eta(3)-coordination found for the Ni and Co complexes.

引用

页码：973 / 974

页数：2

共 16 条

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