(Phosphino-oxazoline)copper(II) complexes as chiral catalysts for enantioselective Diels-Alder reactions

被引：56

作者：

Sagasser, I ^{[1
]}

Helmchen, G ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 3-4期

关键词：

D O I：

10.1016/S0040-4039(97)10570-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Phosphino-oxazoline)copper(II) complexes with bulky aryl groups at phosphorus were found to be excellent catalysts for Diels-Alder additions of 3-acryloyl-1,3-oxazolidin-2-one. Diels-Alder reactions with a range of substrates were investigated. Enantioselectivities of up to 97% ee were achieved. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：261 / 264

页数：4

共 24 条

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