A Novel Example of Molecular Hydrogen Generation from Formic Acid at Visible-Light-Responsive Photocatalyst

被引：55

作者：

Kakuta, Seiji ^{[1
]}

Abe, Toshiyuki ^{[2
]}

机构：

[1] Aomori Prefectural Ind Technol Res Ctr, New Energy Technol Res Sect, Aomori 0300113, Japan

[2] Hirosaki Univ, Grad Sch Sci & Technol, Dept Frontier Mat Chem, Hirosaki, Aomori 0368561, Japan

来源：

ACS APPLIED MATERIALS & INTERFACES | 2009年 / 1卷 / 12期

关键词：

cuprous oxide; formic acid; hydrogen generation; photochemistry; photolysis; WATER; CU2O; NANOPARTICLES; IRRADIATION; REDUCTION; COMPLEXES; ELECTRODE; EVOLUTION; TIO2;

D O I：

10.1021/am900707e

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The photocatalytic decomposition of formic acid (HCOOH) into dihydrogen and carbon dioxide was found to occur at Cu(2)O, particularly without the contamination by CO From the organic acid, This work first demonstrated that the stoichiometric and selective decomposition of HCOOH is induced by a visible-light-responsive photocatalyst.

引用

页码：2707 / 2710

页数：4

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