New approaches to hybrid polymers that contain phosphazene rings

被引:39
作者
Allcock, Harry R. [1 ]
机构
[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
基金
美国国家科学基金会;
关键词
cyclophosphazene; hybrid polymers; electroluminescence; ROMP; ADMET;
D O I
10.1007/s10904-007-9134-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
New methods are described for the incorporation of cyclophosphazene rings into macromolecules. These include polynorbornenes with cyclophosphazene side units produced by ROMP reactions, polystyrenes linked to phosphazene rings by azide coupling processes, and cyclolinear polymers by ADMET and Heck coupling reactions. These last species are wavelength-emission tailored electroluminescent materials.
引用
收藏
页码:349 / 359
页数:11
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WELNA DT, 2006, IN PRESS CHEM MAT