Self-assembly of metallamacrocycles via a rigid phosphorus donor linker

被引：22

作者：

Ghosh, Sushobhan ^{[1
]}

Mukherjee, Partha Sarathi ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 14期

关键词：

D O I：

10.1021/om700296k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination-driven self-assembly of a series of discrete 2D metallomacrocycles from a rigid diphosphine donor linker and Pd/Pt-containing 90 degrees acceptors is described. All these assemblies are characterized by multinuclear NMR and, in four cases, X-ray crystallography. The selective formation of a diphosphine bridged macrocycle, [(en)Pd(mu-trans-PPh2CHCHPPh2)(2)Pd(en)](4+), from a 1:1:1 mixture of cis-Pd(en)(NO3)(2), trans-Ph2PCHCHPPh2, and 1,2-bis(4-pyridyl)ethane is also established.

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收藏

页码：3362 / 3367

页数：6

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