Reactions of [CpRuCl(PP)] (PP = dppm, dppe) with NaBAr′4:: Structural characterization of [{CpRu}2(μ-Cl)(μ-dppm)2][BAr′4] and of [Cp*Ru(N2)(dppm)][BAr′4] (Ar′=3,5-C6H3(CF3)2)

被引：16

作者：

Aneetha, H

Jiménez-Tenorio, M

Puerta, MC

Valerga, P ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Ciencia Mat & Ingn Met & Quim Inorgan, Puerto Real 11510, Cadiz, Spain

[2] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 08期

关键词：

D O I：

10.1021/om020880l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Cp*RuCl(dppm)] with NaBAr′4 in fluorobenzene under argon generates the binuclear complex [{Cp*Ru}2(μ-Cl)(μ-dppm)2] [BAr′4], which has been structurally characterized. No complex was isolated from the reaction of [Cp*RuCl(dppe)] with NaBAr′4 under argon, but halide abstraction from [Cp*RuCl(PP)] (PP = dppm, dppe) under dinitrogen using NaBAr′4 yielded the corresponding cationic terminal dinitrogen complexes [Cp*Ru(N2)(PP)][BAr′4].

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页码：1779 / 1782

页数：4

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