Aza-bis(oxazolines): New chiral ligands for asymmetric catalysis

被引:179
作者
Glos, M [1 ]
Reiser, O [1 ]
机构
[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
关键词
D O I
10.1021/ol005947k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
GRAPHICS Aza-bis(oxazolines) are introduced as chiral ligands for asymmetric catalysis combining the advantages of easy availability of bis(oxazolines) and backbone variability of aza-semicorrins. Especially, the title ligands could be attached to a polymeric support, which allowed the development of easily recoverable copper(I) catalysts for asymmetric cyclopropanation reactions.
引用
收藏
页码:2045 / 2048
页数:4
相关论文
共 68 条
  • [1] Polymer-grafted Ti-TADDOL complexes. Preparation and use as catalysts in Diels-Alder reactions
    Altava, B
    Burguete, MI
    Escuder, B
    Luis, SV
    Salvador, RV
    Fraile, JM
    Mayoral, JA
    Royo, AJ
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (10) : 3126 - 3134
  • [2] THE ASYMMETRIC KHARASCH REACTION - CATALYTIC ENANTIOSELECTIVE ALLYLIC ACYLOXYLATION OF OLEFINS WITH CHIRAL COPPER(I) COMPLEXES AND TERT-BUTYL PERBENZOATE
    ANDRUS, MB
    ARGADE, AB
    CHEN, X
    PAMMENT, MG
    [J]. TETRAHEDRON LETTERS, 1995, 36 (17) : 2945 - 2948
  • [3] Polymer-supported chiral Co(salen) complexes: Synthetic applications and mechanistic investigations in the hydrolytic kinetic resolution of terminal epoxides
    Annis, DA
    Jacobsen, EN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) : 4147 - 4154
  • [4] Preparation and use of a polymer supported BINAP hydrogenation catalyst
    Bayston, DJ
    Fraser, JL
    Ashton, MR
    Baxter, AD
    Polywka, MEC
    Moses, E
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (09) : 3137 - 3140
  • [5] A new class of bis-oxazoline ligands for the Cu-catalysed asymmetric cyclopropanation of olefins
    Bedekar, AV
    Andersson, PG
    [J]. TETRAHEDRON LETTERS, 1996, 37 (23) : 4073 - 4076
  • [6] Investigation of the effects of the structure and chelate size of bis-oxazoline ligands in the asymmetric copper-catalyzed cyclopropanation of olefins: Design of a new class of ligands
    Bedekar, AV
    Koroleva, EB
    Andersson, PG
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (08) : 2518 - 2526
  • [7] BOLM C, 1997, ANGEW CHEM, V109, P773
  • [8] BOLM C, 1997, ANGEW CHEM, P2353
  • [9] BOLM C, 1956, CHEM COMMUN, V21, P1
  • [10] Bolm C., 1991, ANGEW CHEM, V103, P556