Selective Nucleation and Growth of Cu and Ni Core/Shell Nanoparticles

被引:37
作者
Carroll, Kyler J. [1 ]
Calvin, Scott [2 ]
Ekiert, Thomas F. [3 ]
Unruh, Karl M. [3 ]
Carpenter, Everett E. [1 ]
机构
[1] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
[2] Sarah Lawrence Coll, Dept Phys, Bronxville, NY 10708 USA
[3] Univ Delaware, Dept Phys & Astron, Newark, DE 19716 USA
关键词
MAGNETIC NANOPARTICLES; POLYOL PROCESS; PARTICLES;
D O I
10.1021/cm1004032
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple synthesis of core-shell nanoparticles (CSNPs) is reported using a modified polyol process. We found that it is possible to control the nucleation kinetics of nickel and copper salts in ethylene glycol by manipulating the boiling temperature of the solution. It is hypothesized that a 10 °C temperature difference is sufficient to separate out the nucleation of elemental copper and nickel nanoparticles. © 2010 American Chemical Society.
引用
收藏
页码:2175 / 2177
页数:3
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