Scope, limitations and mechanistic aspects in the selective homogeneous palladium-catalyzed reduction of alkenes under transfer hydrogen conditions

被引：40

作者：

Brunel, Jean Michel ^{[1
]}

机构：

[1] Univ Paul Cezanne, Lab Synth & Etude Subst Nat Act Biol, SESNAB, Fac Sci & Tech St Jerome, F-13397 Marseille 20, France

来源：

TETRAHEDRON | 2007年 / 63卷 / 18期

关键词：

palladium; reduction of alkenes; tri-tert-butyl phosphine; transfer hydrogen; catalysis;

D O I：

10.1016/j.tet.2007.01.053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and efficient mild Pd/P(t-BU)(3) catalyst for selective reduction of various alkenes under transfer hydrogen conditions has been developed leading to the corresponding saturated derivatives in chemical yields varying from 65 to 98%. Mechanistic rationale of this reaction has been also demonstrated. (C) 2007 Elsevier Ltd. All rights reserved.

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页码：3899 / 3906

页数：8

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