P(t-Bu)3 :: A versatile and efficient ligand in homogeneous catalysis

被引：20

作者：

Brunel, JM

机构：

[1] Univ Aix Marseille, Lab Synthese, F-13397 Marseille 20, France

[2] Univ Aix Marseille, Fac Sci & Tech St Jerome, INRA 1111, IMRN,Etude Subst Nat Act Biol,SESNAB, F-13397 Marseille, France

来源：

MINI-REVIEWS IN ORGANIC CHEMISTRY | 2004年 / 1卷 / 03期

关键词：

tri-tert-butyl phosphine (P(t-Bu)(3)); palladium; catalysis; amination; cross coupling;

D O I：

10.2174/1570193043403163

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Changing substituents on phosphorus ligands can cause marked changes in the behaviour of the free ligands and of their transition metal complexes. In this review, we will describe the synthesis and the application of P(t-Bu)(3), an efficient ligand in numerous homogeneous catalytic systems and rationalise its singular behaviour.

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收藏

页码：249 / 277

页数：29

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