Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes

被引：53

作者：

Schroeder, Kristin ^{[1
]}

Enthaler, Stephan ^{[2
]}

Join, Benoit ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 10期

关键词：

epoxidation; hydrogen peroxide; iron; mechanistic studies; olefins; 2-HIS-1-CARBOXYLATE FACIAL TRIAD; ASYMMETRIC EPOXIDATION; HYDROGEN-PEROXIDE; ALKENE EPOXIDATION; METHYLTRIOXORHENIUM; OXIDATION; EFFICIENT; COMPLEX; PORPHYRINS; ACTIVATION;

D O I：

10.1002/adsc.201000091

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The combination of iron(III) chloride, pyridine-2,6-dicarboxylic acid and formamidine ligands allows for the epoxidation of styrenes and conjugated dienes in excellent chemoselectivity and yields.

引用

页码：1771 / 1778

页数：8

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