A new approach to symmetric 2,2′:6′,2"-terpyridines

被引：17

作者：

Adrian, JC ^{[1
]}

Hassib, L

De Kimpe, N

Keppens, M

机构：

[1] Union Coll, Dept Chem, Schenectady, NY 12308 USA

[2] State Univ Ghent, Fac Agr & Appl Biol Sci, Dept Organ Chem, B-9000 Ghent, Belgium

来源：

TETRAHEDRON | 1998年 / 54卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(98)00005-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel four step process for the preparation of symmetric terpyridines is presented. The title compound, 2,2':6',2 "-terpyridine (1a) and a substituted derivative, 5,5 "-dimethyl-2,2':6',2 "-terpyridine (1b) are prepared. Both 1a and 1b share a common precursor, 2,6-diacetylpyridine (2) and are prepared in overall yields of 73 and 93% respectively. The purities of the crude terpyridine products are in the 90-95% range. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2365 / 2370

页数：6

共 18 条

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