Synthesis and fluorescence behavior of novel Ru(bpy)3-porphyrin conjugates

被引：14

作者：

Lintuluoto, JM ^{[1
]}

Borovkov, VV ^{[1
]}

Inoue, Y ^{[1
]}

机构：

[1] ERATO, JST, Inoue Photochirogenesis Project, Toyonaka, Osaka 5600085, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)00673-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

No emission of photoexcited Ru(bpy)(3) was found in Fe and Mn porphyrin-Ru(bpy)(3) conjugates. In the case of free-base and Zn porphyrin-Ru(bpy)(3) conjugates, quenching of Ru(bpy)(3) emission and the appearance of considerable free-base and Zn porphyrin emissions were found. The excitation spectra of these emissions revealed however that these emissions originate from the corresponding excitation of free-base and Zn porphyrin moieties. These observations suggest efficient intramolecular electron transfer from the photoexcited Ru(bpy)(3) moiety to the free-base, Zn, Fe and Mn porphyrins. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4781 / 4786

页数：6