Benziodoxole-based hypervalent iodine reagents in organic synthesis

被引：139

作者：

Zhdankin, VV ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Duluth, MN 55812 USA

来源：

CURRENT ORGANIC SYNTHESIS | 2005年 / 2卷 / 01期

关键词：

hypervalent iodine; oxidation; benziodoxole; benziodazole; IBX; DMP;

D O I：

10.2174/1570179052996982

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Five-membered hypervalent iodine heterocycles derived from benziodoxole and benziodazole oxide have recently emerged as reagents of choice for various synthetically useful oxidative transformations. In particular, IBX (2-iodoxylbenzoic acid) and DMP (Dess-Martin periodinane) are widely used for the selective oxidation of primary and secondary alcohols and for a variety of other important oxidations. IBX-amides and IBX-esters are a new class of pentavalent iodine reagents with a pseudo-benziodoxole structure and a reactivity pattern similar to IBX.

引用

页码：121 / 145

页数：25

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