The first proton-conducting metallic ion-radical salts

被引：46

作者：

Akutsu-Sato, A

Akutsu, H

Turner, SS

Day, P

Probert, MR

Howard, JAK

Akutagawa, T

Takeda, S

Nakamura, T

Mori, T

机构：

[1] UCL Royal Inst Great Britain, DFRL, London W1S 4BS, England

[2] Univ Exeter, Sch Biol & Chem Sci, Dept Chem, Exeter EX4 4QD, Devon, England

[3] Univ Durham, Dept Chem, Durham DH1 3LE, England

[4] Univ Hyogo, Grad Sch Mat Sci, Kobe, Hyogo 6781297, Japan

[5] Tokyo Inst Technol, Dept Organ & Polymer Mat, Megaru Ku, Tokyo 1130033, Japan

[6] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[7] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600812, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期

关键词：

conducting materials; electron transport; ion channels; proton transport;

D O I：

10.1002/anie.200461686

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Any old ion? Two bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) radical salts with ion channels of stacked [18]crown-6 and Cat/H2O molecules (Cat = H3O+ or NH4+) are described. The structures contain alternating BEDT-TTF layers, [(Cat)M(C2O 4)3]2- (M = Ga, Cr) layers, and the [18]crown-6 ion channels (see picture). The salts are metallic electrical conductors, and they show high protonic conductivity.

引用

页码：292 / 295

页数：4

共 16 条

[1] Proton transfer and a dielectric phase transition in the molecular conductor (HDABCO+)2(TCNQ)3 [J].