Inclusion compounds of 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol with DMF and DMSO: structures, selectivity and kinetics of desolvation

被引：20

作者：

Caira, MR

Jacobs, A ^{[1
]}

Nassimbeni, LR

Toda, F

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Univ Port Elizabeth, Dept Chem, ZA-6000 Port Elizabeth, South Africa

[3] Okayama Univ Sci, Dept Chem, Okayama, Japan

来源：

CRYSTENGCOMM | 2003年

关键词：

D O I：

10.1039/b302548a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The host (H) 1,1,6,6-tetraphenylhexa-2,4-diyne-1,6-diol includes N, N-dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). The structures of the isostructural inclusion compounds H.2DMF and H.2DMSO have been determined. Competition experiments, kinetics of desolvation and guest exchange reactions were performed and the results rationalised in terms of the structural features of the host - guest compounds.

引用

页码：150 / 153

页数：4