A new route to organic nanotubes from porphyrin dendrimers

被引：163

作者：

Kim, Y ^{[1
]}

Mayer, MF ^{[1
]}

Zimmerman, SC ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 10期

关键词：

coordination polymers; dendrimers; metathesis; nanotubes; porphyrinoids;

D O I：

10.1002/anie.200390295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By chemically cleaving out the core of a dendritic metalloporphyrin coordination polymer, organic nanotubes can be created (see schematic representation). This is made possible by intramolecularly cross-linking the periphery of the oligomer with a ring-closing metathesis reaction prior to coring.

引用

页码：1121 / 1126

页数：6

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