Stannylene insertion into an amino-stabilized iron-silylene complex. Synthesis of [(OC)(3){(Me(2)N)(2)(RO)P}Fe{[NMe(2)Si(OR)(2)(SnNBu(t)SiMe(2)NHBu(t))]}] (R=Me, Et)

被引：9

作者：

Braunstein, P ^{[1
]}

Huch, V ^{[1
]}

Stern, C ^{[1
]}

Veith, M ^{[1
]}

机构：

[1] UNIV SAARLAND,D-66041 SAARBRUCKEN,GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the HNMe(2)-stabilized iron-silylene complexes (1a,b) with the stannylene reagent SnNBu(t)SiMe(2)NBu(t) 2 occurs selectively by insertion into the N-H bond to give novel types of base-stabilized silylene, stannylene complexes.

引用

页码：2041 / 2042

页数：2

共 19 条

[1] BODENSIECK U, 1994, ANGEW CHEM INT EDIT, V33, P2440
[2] SYNTHETIC, SPECTROSCOPIC AND STRUCTURAL STUDIES ON PHOSPHINE-STABILIZED [PPH(3),PH(2)PCH(2)PPH(2),PH(2)P(CH2)(4)PPH(2), (PH(2)P)C5H4N] MAIN-GROUP ELEMENT-IRON-SILICON CHAIN COMPLEXES
BRAUNSTEIN, P
KNORR, M
STRAMPFER, M
DECIAN, A
FISCHER, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (02): : 117 - 134
[3] BRAUNSTEIN P, UNPUB
[4] BRAUNSTEIN P, 1996, J CLUST SCI, V7, P145
[5] COLOMER E, 1981, TOP CURR CHEM, V96, P79
[6] ORGANO-GROUP-13 METAL-COMPLEXES OF THE D-BLOCK ELEMENTS .6. TRANSITION-METAL-SUBSTITUTED VOLATILE ALANES, GALLANES, AND INDANES - SYNTHESIS AND STRUCTURE
FISCHER, RA
BEHM, J
PRIERMEIER, T
SCHERER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (05): : 746 - 748
[7] HUHEEY JE, 1995, ANORGANISCHE CHEM
[8] KAESZ HD, 1990, NEW J CHEM, V14, P527
[9] KNORR M, IN PRESS ORGANOMETAL
[10] SUHR H, 1990, NEW J CHEM, V14, P523

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