ORGANO-GROUP-13 METAL-COMPLEXES OF THE D-BLOCK ELEMENTS .6. TRANSITION-METAL-SUBSTITUTED VOLATILE ALANES, GALLANES, AND INDANES - SYNTHESIS AND STRUCTURE

被引：46

作者：

FISCHER, RA

BEHM, J

PRIERMEIER, T

SCHERER, W

机构：

[1] Anorganisch-chemisches Institut der, Technischen Universität München, Garching, D-W-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 05期

关键词：

D O I：

10.1002/anie.199307461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The instability and tendency to disproportionate of organometallic compounds of Group 13 metal-d-metal complexes were countered by adjusting the donor acceptor properties of the metal centers. Now nothing presents the use of this class of compounds in layering processes or the development of its chemistry. A large number of alanes, gallanes, and indanes related to 1 (M = Fe. L = Cp, n = 2) that are volatile without decomposition were prepared.

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页码：746 / 748

页数：3

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