学术探索
学术期刊
新闻热点
数据分析
智能评审

Influence of ionic liquids on the electrical conductivity and morphology of PEDOT:PSS films

被引：244
作者：
Dobbelin, Markus
Marcilla, Rebeca
Salsamendi, Maitane
Pozo-Gonzalo, Cristina
Carrasco, Pedro M.
Pomposo, Jose A.
Mecerreyes, David
机构：
[1] CIDETEC, New Mat Dept, E-20009 San Sebastian, Spain
[2] CIC NANOGUNE Consolider, E-20009 San Sebastian, Spain
来源：
CHEMISTRY OF MATERIALS | 2007年 / 19卷 / 09期
关键词：
D O I：
10.1021/cm070398z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Small-molecule nonvolatile additives based on ionic liquids (IL) as electrical conductivity enhancer in Poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) was studied. Ionic liquids were investigated in the synthesis of self-assembled, highly organized hybrid nanostructures due to their ability as supramolecular solvents. Different percentage of five ionic liquids, such as 1-butyl-3-methylimidazolium tetrafluoroborate (bmim) F 4 and 1-butyl-3-methylimidazolium bromide (bmim)Br were added to a PEDOT:PSScommercial dispersion. Films of pure PEDOT:PSS showed an average conductivity of 14 S cm-1, which corresponded to the value range given by the supplier. AFM images showed that IL induced the formation of a three-dimensional conducting network with smaller PEDOT domains. The ionic character of the films was significantly increased because of the presence of ionic liquids, which can be used effectively in optoelectronic devices.
引用
收藏
页码：2147 / 2149
页数：3
相关论文
共 26 条
[1]  
[Anonymous], ADV MAT
[2]   Conjugated polymer photovoltaic cells [J].
Coakley, KM ;
McGehee, MD .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542
[3]   The origin of the high conductivity of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS) plastic electrodes [J].
Crispin, X. ;
Jakobsson, F. L. E. ;
Crispin, A. ;
Grim, P. C. M. ;
Andersson, P. ;
Volodin, A. ;
van Haesendonck, C. ;
Van der Auweraer, M. ;
Salaneck, W. R. ;
Berggren, M. .
CHEMISTRY OF MATERIALS, 2006, 18 (18) :4354-4360
[4]   Conductivity, morphology, interfacial chemistry, and stability of poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate): A photoelectron spectroscopy study [J].
Crispin, X ;
Marciniak, S ;
Osikowicz, W ;
Zotti, G ;
Van der Gon, AWD ;
Louwet, F ;
Fahlman, M ;
Groenendaal, L ;
De Schryver, F ;
Salaneck, WR .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2003, 41 (21) :2561-2583
[5]   Use of ionic liquids as electrolytes in electromechanical actuator systems based on inherently conducting polymers [J].
Ding, J ;
Zhou, DZ ;
Spinks, G ;
Wallace, G ;
Forsyth, S ;
Forsyth, M ;
MacFarlane, DR .
CHEMISTRY OF MATERIALS, 2003, 15 (12) :2392-2398
[6]   Laminated fabrication of polymeric photovoltaic diodes [J].
Granström, M ;
Petritsch, K ;
Arias, AC ;
Lux, A ;
Andersson, MR ;
Friend, RH .
NATURE, 1998, 395 (6699) :257-260
[7]  
Groenendaal L.B., 2000, ADV MATER, V12, P481, DOI [DOI 10.1002/(SICI)1521-4095(200004)12:7<LESS, 10.1002/(SICI)1521-4095(200004)12]
[8]  
Holbrey JD, 2003, ACS SYM SER, V856, P121
[9]   The effects of solvents on the morphology and sheet resistance in poly (3,4-ethylenedioxythiophene)-polystyrenesulfonic acid (PEDOT-PSS) films [J].
Jönsson, SKM ;
Birgerson, J ;
Crispin, X ;
Greczynski, G ;
Osikowicz, W ;
van der Gon, AWD ;
Salaneck, WR ;
Fahlman, M .
SYNTHETIC METALS, 2003, 139 (01) :1-10
[10]   Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents [J].
Kim, JY ;
Jung, JH ;
Lee, DE ;
Joo, J .
SYNTHETIC METALS, 2002, 126 (2-3) :311-316
123