TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries

被引:445
作者
Wei, Xiaoliang [1 ]
Xu, Wu [1 ]
Vijayakumar, Murugesan [1 ]
Cosimbescu, Lelia [1 ]
Liu, Tianbiao [1 ]
Sprenkle, Vincent [1 ]
Wang, Wei [1 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99354 USA
关键词
PROGRESS; POLYMERS; STORAGE;
D O I
10.1002/adma.201403746
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
(Figure Presented) A TEMPO-based non-aqueous electrolyte with the TEMPO concentration as high as 2.0 m is demonstrated as a high-energy-density catholyte for redox flow battery applications. With a hybrid anode, Li|TEMPO flow cells using this electrolyte deliver an energy efficiency of ca. 70% and an impressively high energy density of 126 W h L-1. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7649 / 7653
页数:5
相关论文
共 34 条
[1]
An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery [J].
Brushett, Fikile R. ;
Vaughey, John T. ;
Jansen, Andrew N. .
ADVANCED ENERGY MATERIALS, 2012, 2 (11) :1390-1396
[2]
Cappillino P. J., 2014, ADV ENERGY MATER, V4, DOI [10.1002/aenm.201470001, DOI 10.1002/AENM.201470001]
[3]
Semi-Solid Lithium Rechargeable Flow Battery [J].
Duduta, Mihai ;
Ho, Bryan ;
Wood, Vanessa C. ;
Limthongkul, Pimpa ;
Brunini, Victor E. ;
Carter, W. Craig ;
Chiang, Yet-Ming .
ADVANCED ENERGY MATERIALS, 2011, 1 (04) :511-516
[4]
Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[5]
Silicon-Based Non Aqueous Anolyte for Li Redox-Flow Batteries [J].
Hamelet, S. ;
Larcher, D. ;
Dupont, L. ;
Tarascon, J. -M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (03) :A516-A520
[6]
1,3-Dioxolane, tetrahydrofuran, acetylacetone and dimethyl sulfoxide as solvents for non-aqueous vanadium acetylacetonate redox-flow-batteries [J].
Herr, T. ;
Noack, J. ;
Fischer, P. ;
Tuebke, J. .
ELECTROCHIMICA ACTA, 2013, 113 :127-133
[7]
Manipulating surface reactions in lithium-sulphur batteries using hybrid anode structures [J].
Huang, Cheng ;
Xiao, Jie ;
Shao, Yuyan ;
Zheng, Jianming ;
Bennett, Wendy D. ;
Lu, Dongping ;
Saraf, Laxmikant V ;
Engelhard, Mark ;
Ji, Liwen ;
Zhang, Jiguang ;
Li, Xiaolin ;
Graff, Gordon L. ;
Liu, Jun .
NATURE COMMUNICATIONS, 2014, 5
[8]
Multi-electron redox reaction of an organic radical cathode induced by a mesopore carbon network with nitroxide polymers [J].
Huang, Qian ;
Choi, Daiwon ;
Cosimbescu, Lelia ;
Lemmon, John P. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (48) :20921-20928
[9]
Powering up the Future: Radical Polymers for Battery Applications [J].
Janoschka, Tobias ;
Hager, Martin D. ;
Schubert, Ulrich S. .
ADVANCED MATERIALS, 2012, 24 (48) :6397-6409
[10]
Pore-filled anion-exchange membranes for non-aqueous redox flow batteries with dual-metal-complex redox shuttles [J].
Kim, Do-Hyeong ;
Seo, Seok-Jun ;
Lee, Myung-Jin ;
Park, Jin-Soo ;
Moon, Seung-Hyeon ;
Kang, Yong Soo ;
Choi, Young-Woo ;
Kang, Moon-Sung .
JOURNAL OF MEMBRANE SCIENCE, 2014, 454 :44-50