First chemical transformations of lanthanide borohydride compounds:: Synthesis and crystal structures of [(η-C8H8)Nd(BH4)(THF)]2 and [(η-C8H8)Nd(THF)4][BPh4]

被引：102

作者：

Cendrowski-Guillaume, SM ^{[1
]}

Nierlich, M ^{[1
]}

Lance, M ^{[1
]}

Ephritikhine, M ^{[1
]}

机构：

[1] CEA Saclay, CNRS, URA 331, DSM,DRECAM,Serv Chim Mol, F-91191 Gif Sur Yvette, France

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 05期

关键词：

D O I：

10.1021/om9709446

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Nd(BH4)(3)(THF)(3) with K2COT (COT = eta-C8H8) in tetrahydrofuran (THF) gave the first (cyclooctatetraene)lanthanide borohydride, (COT)Nd(BH4)(THF)(2) (1). By treatment with NHEt3BPh4, 1 was transformed into [(COT)Nd(THF)(4)][BPh4] (3), a unique example of a (cyclooctatetraene)lanthanide cation; both 1 and 3 gave (COT)Nd(Cp*)(THF) (Cp* = eta-C5Me5) upon. reaction with KCp*.

引用

页码：786 / 788

页数：3

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