Total syntheses of the alkaloids ipalbidinium and clathryimine B

被引：19

作者：

Daab, JC

Bracher, F

机构：

[1] Univ Munich, Zentrum Pharmaforsch, Dept Pharm, D-81377 Munich, Germany

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Pharmazeut Chem, D-38106 Braunschweig, Germany

来源：

MONATSHEFTE FUR CHEMIE | 2003年 / 134卷 / 04期

关键词：

alkaloids; ipalbidinium; clathryimine B; palladium-catalyzed cross-coupling; halogenation;

D O I：

10.1007/s00706-002-0540-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The indolizidinium alkaloid ipalbidinium and the quinolizidinium alkaloid clathryimine B were prepared starting from brominated 2-aminopyridines using two Pd-catalyzed cross-coupling reactions and a Sandmeyer-type diazotation/iodination protocol as the key steps.

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收藏

页码：573 / 583

页数：11

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