A spin-admixed ruthenium complex

被引：55

作者：

Barral, MC

Herrero, S

Jiménez-Aparicio, R

Torres, MR

Urbanos, FA

机构：

[1] Univ Complutense, Dept Quim Inorgan, E-28040 Madrid, Spain

[2] Univ Complutense, Fac Ciencias Quim, Ctr Asistencia Invest Rayos X, E-28040 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期

关键词：

magnetic properties; metal-metal interactions; N ligands; ruthenium;

D O I：

10.1002/anie.200461463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual magnetic behavior of [Ru2(μ-O2CMe) (μ-DPhF)3(H2O)] BF4·0.5 CH 2Cl2 (1; DPhF = N,N′-diphenylformamidinate), which is intermediate between that of compounds with spin states S = 1/2 and S = 3/2, is attributed to a quantum mechanical spin admixture. This phenomenon results from a multiple bond between the metal atoms which permits an appropriate disposition of molecular orbitals.

引用

页码：305 / 307

页数：3

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