Enantioselective epoxidation catalysed by ruthenium complexes with chiral tetradentate bisamide ligands

被引：72

作者：

End, N ^{[1
]}

Pfaltz, A ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 05期

关键词：

D O I：

10.1039/a708874d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium complexes with chiral bis(dihydrooxazolylphenyl)oxalamide ligands catalyse the-epoxidation of (E)-stilbene and (E)-1-phenylpropene with 69 and 58% ee, respectively, using NaIO4 as oxidant.

引用

页码：589 / 590

页数：2

共 21 条

[1] COMPETITION BETWEEN CATALYTIC EPOXIDATION AND OXIDATIVE CLEAVAGE OF TRANS-STILBENE BY RUTHENIUM COMPLEXES ASSOCIATED WITH BIDENTATE LIGANDS [J].

AUGIER, C ;

MALARA, L ;

LAZZERI, V ;

WAEGELL, B .

TETRAHEDRON LETTERS, 1995, 36 (48) :8775-8778

[2] THE STEREOSPECIFIC EPOXIDATION OF OLEFINS CATALYZED BY RUTHENIUM [J].

BALAVOINE, G ;

ESKENAZI, C ;

MEUNIER, F ;

RIVIERE, H .

TETRAHEDRON LETTERS, 1984, 25 (30) :3187-3190

[3] RUTHENIUM-CATALYZED EPOXIDATIONS - MECHANISTIC AND SYNTHETIC ASPECTS [J].

BARF, GA ;

SHELDON, RA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 102 (01) :23-39

[4] CHROMIUM CATALYZED ASYMMETRIC ALKENE EPOXIDATION - GREATER SELECTIVITY FOR AN E-ALKENE VERSUS ITS Z-ISOMER [J].

BOUSQUET, C ;

GILHEANY, DG .

TETRAHEDRON LETTERS, 1995, 36 (42) :7739-7742

[5] Molar scale synthesis of enantiopure stilbene oxide [J].

Chang, HT ;

Sharpless, KB .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (18) :6456-6457

[6] THREITOL-STRAPPED MANGANESE PORPHYRINS AS ENANTIOSELECTIVE EPOXIDATION CATALYSTS OF UNFUNCTIONALIZED OLEFINS [J].

COLLMAN, JP ;

LEE, VJ ;

KELLENYUEN, CJ ;

ZHANG, XM ;

IBERS, JA ;

BRAUMAN, JI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (02) :692-703

[7] REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS [J].

COLLMAN, JP ;

ZHANG, XM ;

LEE, VJ ;

UFFELMAN, ES ;

BRAUMAN, JI .

SCIENCE, 1993, 261 (5127) :1404-1411

[8]

END N, IN PRESS CHEM EUR J

[9]

END N, 1997, THESIS U BASEL

[10] TUNING OF REACTIVITY IN EPOXIDATION OF ALKENES BY IRON AND RUTHENIUM COMPLEXES ASSOCIATED TO NON-PORPHYRINIC LIGANDS [J].

ESKENAZI, C ;

BALAVOINE, G ;

MEUNIER, F ;

RIVIERE, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (16) :1111-1113

← 1 2 3 →