RUTHENIUM-CATALYZED EPOXIDATIONS - MECHANISTIC AND SYNTHETIC ASPECTS

被引：113

作者：

BARF, GA ^{[1
]}

SHELDON, RA ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,DEPT ORGAN CHEM & CATALYSIS,2628 BL DELFT,NETHERLANDS

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 102卷 / 01期

关键词：

ENANTIOSELECTIVITY; EPOXIDATION; OXYGEN TRANSFER; RUTHENIUM;

D O I：

10.1016/1381-1169(95)00089-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanisms of ruthenium-catalyzed oxygen transfer processes are discussed and an overview is given of the synthesis and application of ruthenium complexes as catalysts for epoxidations, including enantioselective epoxidations.

引用

页码：23 / 39

页数：17

共 104 条

[1] OXIDATION OF ALKENES USING THE RUCL3/PHIO SYSTEM [J].

AGARWAL, DD ;

JAIN, R ;

CHAKRAVORTY, A ;

RASTOGI, R .

POLYHEDRON, 1992, 11 (04) :463-467

[2] A NEW EPOXIDATION CATALYST - THE REACTIVITY AND X-RAY CRYSTAL-STRUCTURE OF [RUO2(BIPY)(IO3(OH)(3))].1.5H2O (BIPY=2,2'-BIPYRIDINE) [J].

BAILEY, AJ ;

GRIFFITH, WP ;

WHITE, AJP ;

WILLIAMS, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (16) :1833-1834

[3] CATALYTIC EPOXIDATION OF ALKENES BY STERICALLY CROWDED RUTHENIUM COMPLEXES [J].

BAILEY, CL ;

DRAGO, RS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (03) :179-180

[4] THE STEREOSPECIFIC EPOXIDATION OF OLEFINS CATALYZED BY RUTHENIUM [J].

BALAVOINE, G ;

ESKENAZI, C ;

MEUNIER, F ;

RIVIERE, H .

TETRAHEDRON LETTERS, 1984, 25 (30) :3187-3190

[5]

BAVALOINE G, 1989, TETRAHEDRON LETT, V30, P5141

[6] RUTHENIUM-CATALYZED OXIDATION OF PRIMARY ALCOHOLS WITH THE NEW OXIDATION SYSTEM N-METHYLMORPHOLINE/HYDROGEN-PEROXIDE [J].

BEHR, A ;

EUSTERWIEMANN, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (1-2) :215-219

[7]

Boschi T, 1994, METALLOPORPHYRINS CA, P239

[8] ALKENE EPOXIDATION BY RUTHENIUM(II) PHOSPHINE COMPLEXES - A KINETIC INVESTIGATION [J].

BRESSAN, M ;

MORVILLO, A .

INORGANIC CHEMISTRY, 1989, 28 (05) :950-953

[9] CATALYTIC EPOXIDATION OF ALKENES BY COORDINATIVELY UNSATURATED PHOSPHINO COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II) [J].

BRESSAN, M ;

MORVILLO, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) :650-651

[10] REACTIONS OF HYDROPEROXIDES WITH METALLOTETRAPHENYLPORPHYRINS IN AQUEOUS-SOLUTIONS [J].

BRUICE, TC .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (08) :243-249

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