Hydrothermal synthesis of an open-framework manganese oxalate incorporating KCl chains

被引:9
作者
Vaidhyanathan, R [1 ]
Natarajan, S [1 ]
Rao, CNR [1 ]
机构
[1] Indian Inst Sci, Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India
关键词
ceramics; microporous materials; halides; nanocomposites; structural materials;
D O I
10.1016/S0025-5408(02)01058-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A manganese oxalate of the composition, K-2[Mn-2(C2O4)(3)]2[KCl].2H(2)O, containing metal oxalate layers connected by monodentate oxalate units has been synthesized hydrothermally. An unique feature of this material is that it contains K-Cl chains with a K-Cl distance of similar to3.2 Angstrom, close to the value in bulk KCl. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:477 / 483
页数:7
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