The effect of polymer molecular weight on the formation and evolution of silver-polymer nanocomposite thin films

被引:4
作者
D'Urso, L [1 ]
Nicolosi, V [1 ]
Compagnini, G [1 ]
Puglisi, O [1 ]
机构
[1] Univ Catania, Ist Nazl Fis Mat, Dipartimento Sci Chim, I-95125 Catania, Italy
来源
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS | 2003年 / 23卷 / 1-2期
关键词
silver; polymeric thin films; nanoconposite material;
D O I
10.1016/S0928-4931(02)00241-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silver-poly(methyl methacrylate) nanocomposite thin films (0.1 - 1 mum) have been obtained by in situ self-reduction of an organometallic compound formerly embedded in the polymer structure. The reduction has been obtained through thermal treatments, leading to the formation of Ag particles in the size range 5-50 nm, homogeneously dispersed in the film structure. Nearly monodisperse polymer macromolecules have been used to study the effect of polymer molecular weight (MW) on the formation and evolution of particles. It was found that changes in the polymer molecular weight produce different average particle size which drive the film properties. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:307 / 310
页数:4
相关论文
共 18 条
[1]   Nanocomposite materials for optical applications [J].
Beecroft, LL ;
Ober, CK .
CHEMISTRY OF MATERIALS, 1997, 9 (06) :1302-1317
[2]   BLUE SHIFT OF THE DIPOLAR PLASMA RESONANCE IN SMALL SILVER PARTICLES ON AN ALUMINA SURFACE [J].
BORENSZTEIN, Y ;
DEANDRES, P ;
MONREAL, R ;
LOPEZRIOS, T ;
FLORES, F .
PHYSICAL REVIEW B, 1986, 33 (04) :2828-2830
[3]   Structure and properties of silver nanoparticles dispersed in SiO2 thin films obtained by in situ self-reduction [J].
Compagnini, G ;
D'Urso, L ;
Puglisi, O .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2002, 19 (1-2) :295-298
[4]  
COMPAGNINI G, 2001, J MAT RES, V16
[5]   ULTRAVIOLET VISIBLE ABSORPTION-SPECTRA OF THE COLLOIDAL METALLIC ELEMENTS [J].
CREIGHTON, JA ;
EADON, DG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (24) :3881-3891
[6]   Silver nanoparticles dispersed in polyimide thin film matrix [J].
Fragalà, ME ;
Compagnini, G ;
Malandrino, G ;
Spinella, C ;
Puglisi, O .
EUROPEAN PHYSICAL JOURNAL D, 1999, 9 (1-4) :631-633
[7]   Synthesis, x-ray structure, and characterization of Ag(hfa)•tetraglyme [hfa = hexafluoroacetylacetonate]:: A novel adduct for the fabrication of metallic silver based films via in situ self reduction [J].
Fragalà, ME ;
Malandrino, G ;
Puglisi, O ;
Benelli, C .
CHEMISTRY OF MATERIALS, 2000, 12 (02) :290-+
[8]  
GODOVSKI DY, 1995, ADV POLYM SCI, V119, P79
[9]   CHEMICAL CATALYSIS BY COLLOIDS AND CLUSTERS [J].
LEWIS, LN .
CHEMICAL REVIEWS, 1993, 93 (08) :2693-2730
[10]  
LIDE RD, 1998, CRC HDB CHEM PHYSICS