Preparation of poly(2,3,4,5,6-pentafluorostyrene) and block copolymers with styrene by ATRP

被引：96

作者：

Jankova, K ^{[1
]}

Hvilsted, S ^{[1
]}

机构：

[1] Tech Univ Denmark, Danish Polymer Ctr, Dept Chem Engn, DK-2800 Lyngby, Denmark

来源：

MACROMOLECULES | 2003年 / 36卷 / 05期

关键词：

D O I：

10.1021/ma021039m

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A report on the polymerization of 2,3,4,5,6-pentafluorostyrene using atom transfer radical polymerization (ATRP), involving both homo- and block copolymerization with styrene was presented. The kinetic analysis revealed the polymerization to be first order with respect to monomer up to almost 48% monomer conversion. As the conversion was relatively fast, this reflected the electron withdrawing character of the fluorines on the phenyl ring.

引用

页码：1753 / 1758

页数：6

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