Regioselective bromination and subsequent Suzuki cross-coupling of highly electron deficient 5,10,15,20-tetrakis(trifluoromethyl)porphyrin

被引：40

作者：

Tse, MK ^{[1
]}

Zhou, ZY ^{[1
]}

Mak, TCW ^{[1
]}

Chan, KS ^{[1
]}

机构：

[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

TETRAHEDRON | 2000年 / 56卷 / 39期

关键词：

tetrakis(trifluoromethyl) porphyrin; monobromination; Suzuki cross-coupling;

D O I：

10.1016/S0040-4020(00)00697-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5,10,15,20-Tetrakis(trifluoromethyl)prophyrin zinc complex 2 has been shown to undergo monobromination and regioselective dibromination to give beta-bromoporphyrins 3a-c. The free base beta-bromoporphyrins 4a,b are converted to aryl porphyrins through Suzuki cross-coupling reaction: (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7779 / 7783

页数：5

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