Dynamics and thermodynamics of complex fluids.: II.: Illustrations of a general formalism

被引:626
作者
Öttinger, HC [1 ]
Grmela, M
机构
[1] Swiss Fed Inst Technol, Dept Mat, Inst Polymers, CH-8092 Zurich, Switzerland
[2] Swiss FIT Rheoctr, CH-8092 Zurich, Switzerland
[3] Ecole Polytech, Montreal, PQ H3C 3A7, Canada
来源
PHYSICAL REVIEW E | 1997年 / 56卷 / 06期
关键词
D O I
10.1103/PhysRevE.56.6633
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
For a number of well-known time-evolution equations for nonequilibrium systems we extract a common structure from these equations, referred to as a general equation for the nonequilibrium reversible-irreversible coupling (GENERIC). This fundamental structure is determined by four building blocks, two "potentials" (total energy and entropy) and two "matrices." We illustrate for various examples how three of the four building blocks can be determined in a rather straightforward manner so that, within our GENERIC approach to nonequilibrium dynamics, understanding pf a given nonequilibrium system is reduced to determining a single "metric matrix," or friction matrix, either empirically or by more microscopic considerations. In formulating nonisothermal polymer kinetic theories, we show how the general structure provides a clear distinction between spring potentials of energetic and entropic origins in the various time-evolution equations.
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页码:6633 / 6655
页数:23
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