When electron exchange is chemical exchange assignment of 1H NMR spectra of paramagnetic cobalt(II)-2,2′:6′2"-terpyridine complexes

被引：35

作者：

Chow, HS ^{[1
]}

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Kulicke, KJ ^{[1
]}

Tao, YQ ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

DALTON TRANSACTIONS | 2005年 / 02期

关键词：

D O I：

10.1039/b415419c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electron exchange between [Co(terpy)(2)](3+) and [Co(terpy)(2)](2+) can be monitored by H-1 NMR exchange spectroscopy and allows the cobalt(II) spectra to be fully assigned.

引用

页码：236 / 237

页数：2

共 31 条

[1] ELECTRON TRANSFER IN THE SYSTEM, TRIS-(1,10-PHENANTHROLINE)-COBALT(II)-TRIS-(1,10-PHENANTHROLINE)-COBALT(III) [J].

BAKER, BR ;

BASOLO, F ;

NEUMANN, HM .

JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (03) :371-378

[2]

Batterham T. J., 1973, NMR SPECTRA SIMPLE H

[3] Electron exchange reaction of bis(terpyridine)cobalt(3+/2+) re-examined by NMR [J].

Beattie, JK ;

Elsbernd, H .

INORGANICA CHIMICA ACTA, 1995, 240 (1-2) :641-644

[4] DYNAMICS OF COBALT(II) SPIN-EQUILIBRIUM COMPLEXES [J].

BEATTIE, JK ;

BINSTEAD, RA ;

KELSO, MT ;

DELFAVERO, P ;

DEWEY, TG ;

TURNER, DH .

INORGANICA CHIMICA ACTA, 1995, 235 (1-2) :245-251

[5]

BERTINI I, 1996, COORD CHEM REV, V150

[6]

BRISIG B, UNPUB

[7]

Chow H.-Y., UNPUB

[8] Redistribution of terpy ligands - approaches to new dynamic combinatorial libraries [J].

Constable, EC ;

Housecroft, CE ;

Kulke, T ;

Lazzarini, C ;

Schofield, ER ;

Zimmermann, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (19) :2864-2871

[9] THE COORDINATION CHEMISTRY OF 2,2'-6',2''-TERPYRIDINE AND HIGHER OLIGOPYRIDINES [J].

CONSTABLE, EC .

ADVANCES IN INORGANIC CHEMISTRY, 1986, 30 :69-121

[10]

Constable EC, 1997, NEW J CHEM, V21, P1091

← 1 2 3 4 →