Hydrogenation of silyl-substituted alkynes using diimide: Application to the synthesis of saturated sila-macrocycles

被引：11

作者：

Kwon, E ^{[1
]}

Sakamoto, K ^{[1
]}

Kabuto, C ^{[1
]}

Kira, M ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 12期

关键词：

D O I：

10.1246/cl.2000.1416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrogenation of bistrimethylsilylactylene, bis(trimethylsilyl)-1,3-diynes, and related silylalkynes giving the corresponding saturated compounds were achieved by using diimide prepared in situ from p-toluenesulfonyl hydrazide in diglyme. The present method was applicable to the synthesis of saturated 12- and 18-membered oligosilacycloalkanes.

引用

页码：1416 / 1417

页数：2

共 9 条

[1] PERICYCLYNOSILANES - SYNTHESIS OF A NEW CLASS OF CYCLIC ORGANO-SILICON COMPOUNDS [J].

BORTOLIN, R ;

PARBHOO, B ;

BROWN, SSD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (16) :1079-1081

[2] REDUCTION OF ISOLATED OLEFINIC BONDS BY MEANS OF RHO-TOLUENESULFONYLHYDRAZINE [J].

DEWEY, RS ;

VANTAMELEN, EE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (17) :3729-&

[3]

ICHINOHE M, 1997, 73 ANN M CHEM SOC JA

[4]

KOMAROV NV, 1967, ZH OBSHCH KHIM, V37, P264

[5] Silylacetylene dendrimers: synthesis and characterization [J].

Matsuo, T ;

Uchida, K ;

Sekiguchi, A .

CHEMICAL COMMUNICATIONS, 1999, (18) :1799-1800

[6] A USEFUL METHOD IN ORGANOTIN CHEMISTRY - DIIMINE HYDROGENATION OF 1,2-BIS(TRIMETHYLSTANNYL)-1-ALKENES, 1-TRIMETHYLSILYL-2-TRIMETHYLSTANNYL-1-ALKENES AND SOME DISTANNACYCLOPENTENES [J].

MITCHELL, TN ;

KOWALL, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 481 (01) :137-142

[7]

OVCHINNIKOV YE, 1986, MAKROMOL CHEM, V187, P2011

[8]

Pasto D.J., 1991, ORG REACT, V40, P91, DOI 10.1002/0471264180.or040.02

[9] Silapericyclyne, (Ph2SiCC)6:: Spontaneous conformational resolution of boat- and chair-'exploded' cyclohexane [J].

Unno, M ;

Saito, T ;

Matsumoto, H .

CHEMISTRY LETTERS, 1999, (11) :1235-1236

← 1 →