Self-assembly of positively charged discotic PAHs:: From nanofibers to nanotubes

被引:127
作者
Wu, Dongqing [1 ]
Zhi, Linjie [1 ]
Bodwell, Graham J. [1 ]
Cui, Guanglei [1 ]
Tsao, Nok [1 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
amphiphiles; nanostructures; polycyclic aromatic hydrocarbons; self-assembly; transmission electron microscopy;
D O I
10.1002/anie.200700515
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Mind your PQPs: 1D nanostructures were fabricated by the self-assembly of amphophilic centrally charged discotic 9-alkyl-2- phenylbenzo[8,9]quinolizino[4,5,6,7-fed]-phenanthridinylium (PQP) salts. Increasing the alkyl chain length of the PQP salts resulted in nanoscaled lamellar structures, whereas changing the counterion of the PQP salts from Cl- to BF4- led to a change from nanoribbons to helices and tubes. © 2007 Wiley-VCH Verlag GmbH S. Co. KGaA.
引用
收藏
页码:5417 / 5420
页数:4
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