Selective ion-exchange intercalation of isomeric dicarboxylate anions into the layered double hydroxide [LiAl2(OH)6]Cl•H2O

被引：172

作者：

Fogg, AM ^{[1
]}

Dunn, JS ^{[1
]}

Shyu, SG ^{[1
]}

Cary, DR ^{[1
]}

O'Hare, D ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 01期

关键词：

D O I：

10.1021/cm9705202

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The dicarboxylate anions 1,4-benzenedicarboxylate and fumarate can be selectively intercalated into the layered double hydroxide [LiAl2(OH)(6)]Cl . H2O from equimolar molar mixtures of the 1,2-, 1,3-, and 1,4-benzenedicarboxylate and fumarate and maleate isomers, respectively. Time-resolved in situ energy-dispersive X-ray diffraction studies have shown that these are the thermodynamic products following the conversion of an initial phase in which all the anions are simultaneously intercalated.

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页码：351 / 355

页数：5

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