Re(CO)5Br-catalyzed coupling of epoxides with CO2 affording cyclic carbonates under solvent-free conditions

被引：91

作者：

Jiang, JL ^{[1
]}

Gao, FX ^{[1
]}

Hua, RM ^{[1
]}

Qiu, XQ ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 01期

关键词：

D O I：

10.1021/jo0485785

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of a catalytic amount of Re(CO)(5)Br, the coupling of epoxides with supercritical CO2 without an organic solvent at 110 degreesC has afforded cyclic carbonates in good to excellent yields.

引用

页码：381 / 383

页数：3

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