Polycondensation of diarylsilanes with aromatic dithiols and the model reaction involving RhCl(PPh(3))(3)-catalyzed Si-S bond formation

被引：25

作者：

Baruah, JB ^{[1
]}

Osakada, K ^{[1
]}

Yamamoto, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 01期

关键词：

D O I：

10.1021/om9507181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polymerization of Ar2SiH2 (Ar = Ph, p-MeC(6)H(4), and m-MeC(6)H(4)) with 1,3- and with 1,4-benzenedithiol proceeds at 90-110 degrees C to give the polymers -[(SiAr2)-S-C6H4-S-](n)- with M(w) values in the range (1.5-7.0) x 10(3), based on a polystyrene standard.

引用

页码：456 / 459

页数：4

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