Conversion of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes into (enamine)tricarbonyliron(0) complexes

被引：11

作者：

Ackland, MJ

Danks, TN ^{[1
]}

Howells, ME

机构：

[1] Univ Surrey, Dept Chem, Guildford GU2 5XH, Surrey, England

[2] Pharmacia & Upjohn Inc, Crawley RH10 2LZ, Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 04期

关键词：

D O I：

10.1039/a704588c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes with lithium diethylamide followed by a proton source leads to the formation of (enamine)tricarbonyliron(0) complexes in good yield.

引用

页码：813 / 817

页数：5

共 20 条

[11]

DEPUY CH, 1968, J CHEM SOC CHEM COMM, P1225

[12]

FEWKES EJ, 1987, TETRAHEDRON LETT, V28, P1597

[13]

FRANCKNEUMANN M, 1975, TETRAHEDRON LETT, P1759

[14] PI COORDINATION OF UNSATURATED BONDS CONTAINING HETEROATOMS .2. IRON CARBONYL COMPLEXES OF AZOMETHINE ANALOGS OF 1,3-DIENES . PREPARATION AND NATURE OF COORDINATION BONDINGS [J].

OTSUKA, S ;

YOSHIDA, T ;

NAKAMURA, A .

INORGANIC CHEMISTRY, 1967, 6 (01) :20-&

[15] NOVEL-APPROACH TO FORMATION OF QUATERNARY CENTERS AND INTRODUCTION OF ANGULAR SUBSTITUENTS BY USING TRICARBONYLDIENEIRON COMPLEXES [J].

PEARSON, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (18) :2069-2074

[16] NUCLEAR MAGNETIC RESONANCE SPECTRA OF CYCLOBUTADIENE- AND BUTADIENE-IRON CARBONYL COMPLEXES [J].

PRESTON, HG ;

DAVIS, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (07) :1585-&

[17] A NEW METHOD FOR THE SYNTHESIS OF IRON AZADIENE AND DIENE COMPLEXES - REACTION OF (ETA-2-RCHCHCOR')FE(CO)4 WITH ANILINE AND YLIDE [J].

SEMMELHACK, MF ;

CHENG, CH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 393 (02) :237-241

[18]

Shriver D. F., 1986, MANIPULATION AIR SEN

[19] SIMPLE METHOD FOR DISENGAGEMENT OF ORGANIC LIGANDS FROM IRON COMPLEXES [J].

SHVO, Y ;

HAZUM, E .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (09) :336-337

[20] STUDIES ON OLEFIN-COORDINATING TRANSITION-METAL CARBENE COMPLEXES .9. SYNTHESIS, STRUCTURE, AND REACTIVITIES OF NOVEL CHELATED (ETA-4-STYRENE)DICARBONYL[ETHOXY(AMINO)CARBENE]IRON COMPLEXES [J].

YIN, JG ;

CHEN, JB ;

XU, WH ;

ZHANG, ZY ;

TANG, YQ .

ORGANOMETALLICS, 1988, 7 (01) :21-25

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