Reversible 1,4-cyclo addition of singlet oxygen to N-substituted 2-pyridones:: 1,4-endoperoxide as a versatile chemical source of singlet oxygen

被引：49

作者：

Matsumoto, M ^{[1
]}

Yamada, M ^{[1
]}

Watanabe, N ^{[1
]}

机构：

[1] Kanagawa Univ, Dept Mat Sci, Hiratsuka, Kanagawa 2591293, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 04期

关键词：

D O I：

10.1039/b414845b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-substituted pyridones (1) easily undergo singlet oxygenation to give exclusively the corresponding endoperoxides (2), which decompose to give pyridones again while liberating O-1(2) in high yield.

引用

页码：483 / 485

页数：3

共 17 条

[11] FORMATION OF SUPEROXIDE ION FROM SINGLET OXYGEN - ON THE USE OF A WATER-SOLUBLE SINGLET OXYGEN SOURCE [J].

SAITO, I ;

MATSUURA, T ;

INOUE, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :188-190

[12] METHYL-SUBSTITUTED POLY(VINYLNAPHTHALENE) AS A REVERSIBLE SINGLET OXYGEN CARRIER [J].

SAITO, I ;

NAGATA, R ;

MATSUURA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (22) :6329-6334

[13] DETECTION AND TRAPPING OF A CHEMILUMINESCENT ORTHO-XYLYLENE PEROXIDE - CHEMICAL LIGHT FORMATION ALONG 2 SEPARATE PATHS [J].

SMITH, JP ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2564-2566

[14] CHEMI-LUMINESCENCE OF ORGANIC PEROXIDES - THERMAL GENERATION OF AN ORTHO-XYLYLENE PEROXIDE [J].

SMITH, JP ;

SCHROCK, AK ;

SCHUSTER, GB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (04) :1041-1047

[15] MECHANISM OF THERMOLYSIS OF ENDOPEROXIDES OF AROMATIC-COMPOUNDS - ACTIVATION PARAMETERS, MAGNETIC-FIELD, AND MAGNETIC ISOTOPE EFFECTS [J].

TURRO, NJ ;

CHOW, MF ;

RIGAUDY, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) :7218-7224

[16]

TURRO NJ, 1977, J AM CHEM SOC, V101, P1300

[17] High-pressure, high-efficiency operation of a chemical oxygen-iodine laser [J].

Wani, F ;

Endo, M ;

Fujioka, T .

APPLIED PHYSICS LETTERS, 1999, 75 (20) :3081-3083

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