Hydroformylation of high olefin in biphasic catalytic system: effect of electronic and steric factor of phosphine ligands

被引：13

作者：

Wang, X ^{[1
]}

Fu, HY ^{[1
]}

Li, XJ ^{[1
]}

Chen, H ^{[1
]}

机构：

[1] Sichuan Univ, Minist Educ, Key Lab Green Chem & Technol, Inst Homogeneous Catalysis,Coll Chem, Chengdu 610064, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2004年 / 5卷 / 12期

关键词：

biphasic catalytic system; water-soluble phosphine; hydroformylation;

D O I：

10.1016/j.catcom.2004.09.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Water-soluble ligands, tri[4-methoxyl-3-(sodium sulfonato)phenyl]phosphine (4-MOTPPTS) and tri[2-methoxyl-3-(sodium sulfonato)phenyl]phosphine (2-MOTPPTS) were synthesized and their application as ligand in Rh-catalyzed hydroformylation of higher olefin was investigated in aqueous biphasic catalytic system. The electron-donating methoxyl group of aromatic ring in phosphine ligand induced the decrease of the activity and selectivity for aldehyde of Rh catalyst than TPPTS used as ligand. The Rh catalyst with more crowded and basic 2-MOTPPTS showed lower activity than 4-MOTPPTS. (C) 2004 Elsevier B.V. All rights reserved.

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页码：739 / 741

页数：3

相关论文

共 11 条

[1] Rhodium catalyzed hydroformylation of β-pinene and camphene:: effect of phosphorous ligands and reaction conditions on diastereoselectivity [J].

Barros, HJV ;

Ospina, ML ;

Arguello, E ;

Rocha, WR ;

Gusevskaya, EV ;

dos Santos, EN .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 671 (1-2) :150-157

[2] Micellar effect in high olefin hydroformylation catalyzed by water-soluble rhodium complex [J].

Chen, H ;

Li, YZ ;

Chen, JR ;

Cheng, PM ;

He, YE ;

Li, HJ .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 149 (1-2) :1-6

[3]

Cornils B., 2006, Aqueous -Phase Organometallic Catalysis: Concepts and Applications

[4] HYDROFORMYLATION OF ALKENES BY USE OF RHODIUM COMPLEX CATALYSTS [J].

EVANS, D ;

OSBORN, JA ;

WILKINSON, G .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (12) :3133-+

[5] SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS USING RUTHENIUM OR RHODIUM COMPLEXES OF SULFONATED PHOSPHINES [J].

GROSSELIN, JM ;

MERCIER, C ;

ALLMANG, G ;

GRASS, F .

ORGANOMETALLICS, 1991, 10 (07) :2126-2133

[6] A direct approach to selective sulfonation of triarylphosphines [J].

Gulyás, H ;

Szollosy, A ;

Hanson, BE ;

Bakos, J .

TETRAHEDRON LETTERS, 2002, 43 (14) :2543-2546

[7] Amphiphilic phosphines for catalysis in the aqueous phase [J].

Hanson, BE ;

Ding, H ;

Kohlpaintner, CW .

CATALYSIS TODAY, 1998, 42 (04) :421-429

[8] CTAB micelles and the hydroformylation of octene with rhodium/TPPTS catalysts - Evidence for the interaction of TPPTS with micelle surfaces [J].

Riisager, A ;

Hanson, BE .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 189 (02) :195-202

[9] Multidentate phosphanes as ligands in rhodium catalyzed hydroformylation of 1-hexene [J].

Suomalainen, P ;

Laitinen, R ;

Jääskeläinen, S ;

Haukka, M ;

Pursiainen, JT ;

Pakkanen, TA .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 179 (1-2) :93-100

[10] Hydroformylation of 1-hexene and propene with in situ formed rhodium phosphine catalysts [J].

Suomalainen, P ;

Reinius, HK ;

Riihimäki, H ;

Laitinen, RH ;

Jääskeläinen, S ;

Haukka, M ;

Pursiainen, JT ;

Pakkanen, TA ;

Krause, AOI .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 169 (1-2) :67-78